云南省高校化学分离富集与应用重点实验室于2018年获批，现依托于太阳集团见好就收9728应用化学系，有化学一级学科硕士点和应用化学本科专业。实验室现有科研人员及教师20人，其中教授8人、副教授8人，博士16人；博导4人、硕导16人；省中青年学术和技术带头人2人、省“青千”3人、省师德标兵1人、校级教学名师1人。

实验室成员在研国家自然科学基金7项、高端人才配套项目3项，校企合作项目10余项，近5年，总经费超过1500万元；先后出版教材7部，专著3部，近3年在国内外权威期刊发表高质量论文60余篇，获国家发明专利授权28件。

实验室现有4个主要研究方向：

1.稀贵金属绿色化学分离与富集方法及应用方向：主要研究绿色提金方法和伴生矿物表面催化；高选择性吸附材料的开发及应用；难处理金矿资源的开发利用技术。

2.金属电沉积与溶蚀方向：制备有色金属电积用改性复合电极材料，获得最佳制备技术体系；探究电极在提高阴极产品纯度、降低槽电压和改善阴极产品质量方面的本质原因和电化学特性；阳极氧化复合电沉积机理；活性层微观组织结构变化与其内应力、结合力、析氧过电位、电催化活性、耐腐蚀性等物理及电化学性能的关系及规律。

3.功能化唑类设计与合成方向：通过碳-碳、碳-氮、碳-氧、碳-硅、碳-卤及碳-氢键活化等途径，选择性设计并合成多种类型功能化唑类衍生物，进一步研究其分子间的强、弱相互作用对目标金属的行为作用及影响，从而调节并控制金属的析出与成长，实现过程与产品的选择性控制。

4.复杂样品前处理技术及分离材料的合成：基于超分子识别理论，制备适宜于溶液中重金属离子选择性分离富集的分子/离子印迹材料，阐明分离富集过程中的分子识别机理。

实验室负责人：

胡显智 教授 博士生导师 首席教授

陈阵 教授 博士生导师 实验室主任

骨干成员：

曲雯雯 博士 教 授 博士生导师

李  玮 博士 教 授 博士生导师

王  虹  教授 硕士生导师

江玉波 博士 教授 硕士生导师

许志刚 博士 教授 硕士生导师

冯月斌 博士 教授 硕士生导师

字富庭 博士 副教授 硕士生导师

杨保民 高级工程师 硕士生导师

成会玲 博士 副教授 硕士生导师

杨 睿 博士 副教授 硕士生导师

王月平 博士 副教授 硕士生导师

曹 梅 博士 副教授 硕士生导师

余 强  博士 副教授 硕士生导师

秦贵平  博士 副教授 云南省青年人才

肖铁波  博士 云南省青年人才

陈云龙  博士

周  为  博士

杨 朋 博士生 工程师

朱 薇 博士生 工程师

代表性论文

[1] Peng Yang, Xianzhi Hu, Futing Zi, BaominYang, Qiang Wang, Yunlong Chen, Shuliang Chen. Synergistic enhancement of fine-kaolinite-particle hydrophobic agglomeration by combining dodecylamine with octanoic acid, Minerals Engineering 2020,155.

[2] Yunlong Chen, Futing Zi, Xianzhi Hu, Hong Yu, Yanhe Nie, PengYang, Huiling Cheng. Grafting of organic sulfur-containing functional groups on activated carbon for gold(I) adsorption from thiosulfate solution, Hydrometallurgy ,2019,185,102-110.

[3] Shuliang Chen, Futing Zi, Xianzhi Hu, Yunlong Chen, PengYang, QiangWang, Xuecong Qin. Interfacial properties of mercaptopropyl-functionalised silica gel and its adsorption performance in the recovery of gold(I) thiosulfate complex, Chemical Engineering Journal 2020,393.

[4] Chaowu Wang, Shuliang Chen, Yunlong Chen, Futing Zi, Xianzhi Hu, Xuecong Qin, Yan Zhang. Modification of activated carbon by chemical vapour deposition through thermal decomposition of thiourea for enhanced adsorption of gold thiosulfate complex, Separation and Purification Technology 2020,241 , 116632.

[5] Qiang Wang, Xianzhi Hu, Futing Zi, PengYang, Yunlong Chen, Shuliang Chen. Environmentally friendly extraction of gold from refractory concentrate using a copper - ethylenediamine - thiosulfate solution, Journal of Cleaner Production2019, 214 , 860-872.

[6] Lai Gui, Zhen Chen*, Bangyao Chen, Yuzhu Song, Qiang Yu, Wei Zhu, Qi Hu; Yuanyuan Liu, Zhaoyi Zheng, Ze Lv, Hongjun You, Farhana Yeasmin,  Preparation and characterization of ZnO/PEG-Co(II)-PbO2 nanocomposite electrode and an investigation of the electrocatalytic  degradation of phenol,Journal of Hazardous Materials, 2020, 399:123018-123032.

[7] Gui Lai, Chen Zhen*, Song Yuzhu, Wei Zhu, Qiang Yu, Dan Wu, Tao Zheng,  Preparation and Electrocatalytic Performance of Nanosphere Array PbO2 Electrode on Stainless Steel-Based Grid-Like ZnO Film, Journal of the Electrochemical Society, 2019, 166(12): E384-E393.

[9] YuZhu Song, Chen Zhen*, Gui Lai, Yu Qiang, Zhu Wei, Wu Dan, Zheng Tao,  Fabrication and Electrocatalytic Performance of a Two-Dimensional β-PbO2Macroporous Array for Methyl Orange Degradation, International Journal of Electrochemical Science, 2019, 14: 7790-7810.

[10] Li Huixi, Chen Zhen*, Yu Qiang, Wei Zhu, Wenrong Cui, Electrocatalytic Activity of Ti/Al/Ti/PbO2-WC Rod Composite Electrodes During Zinc Electrowinning, International Journal of Electrochemical Science, 2018, 13:4367-4378.

[11]Zhaoyi Zheng, Qiang Yu*, Zhen Chen, Wei Zhu, Qi Hu, Yuanyuan Liu, Lai Gui, Yuzhu Song, Investigation of localized electrochemical reactivity on a β-PbO2 electrode using scanning electrochemical microscopy, Journal of Electroanalytical Chemistry, 2020, 878: 114699-114706.

[12] Qi Hu, Qiang Yu*, Zhen Chen, Wei Zhu, Yuanyuan Liu, Zhaoyi Zheng, Lai Gui,  Yuzhu Song, Controllable Preparation of a Three-Dimensional Porous Lead Dioxide Electrode with an Oxygen Bubble Template and Its Electrocatalytic Performance, International Journal of ELECTROCHEMICAL SCIENCE, 2021,16: 1507124-1507144.

[13] Yuanyuan Liu, Wei Zhu*, Zhen Chen, Qiang Yu, Qi Hu, Zhaoyi Zheng, Lai Gui, Yuzhu Song, Preparation of cobalt-manganese-modified lead dioxide anodes and the study of their electrochemical performance in electrowinning copper,International Journal of Hydrogen Energy, 2021,46(9):6380-6394.

[14] 李会喜，崔文蓉， 朱薇， 陈阵*， 余强， 电流密度对Ti/β-PbO2-WC复合电极材料在电解锌液中耐蚀性影响研究, 化学研究与应用, 2018, 30(02): 226-230.

[15] Weigen. Du, Hongtai. Huang, Tiebo. Xiao, Yubo. Jiang, Metal-Free, Visible-Light Promoted Intramolecular Azole C- H Bond Amination Using Catalytic Amount of I2: A Route to 1,2,3- Triazolo[1,5-a]quinazolin-5(4H)-ones, Adv. Synth. Catal. 2020, 362, 5124–5129.

[16] Xianyuan. Ma, Weigen. Du, E. A. Anderson, Yubo. Jiang, Copper-Catalyzed Intramolecular C-H Alkoxylation of Diaryltriazoles: Synthesis of Tricyclic Triazole Benzoxazines Org. Lett. 2020, 22, 5320-5325.

[17] Yongsheng. Ren, Tiebo. Xiao, Y. Jiang, Palladium-catalyzed selective ortho C-H alkoxylation at 4-aryl of 1, 4-disubstituted 1, 2, 3-triazoles Tetrahedron 2020, 76, 130985− 130989.

[18] Jiazhuang. Wang,  Guiping. Qin, Tiebo. Xiao, Yubo. Jiang, Synlett 2019, 1452−1456.

[19] Wang Lu, Liu Chao, Wenwen Qu *, Shengming Xu, Libo Zhang *, Jinhui Peng, Xiaolei Ye. Ultrasound-assisted Oil removal of γ-Al2O3-based spent hydrodesulfurization catalyst and Microwave roasting recovery of metal Mo. Ultrasonics Sonochemistry. 2018. 49: 24-32.

[20]Ye Xiaolei, Sivasankar koppala, Qu Wenwen*, Xu Shengming, Zhang Libo, Liu Bingguo, Guo Shenghu*, Wang Lu. New Approach to the Utilization of microwave Thermal Energy: Desulfurization and Decarburization of Spent Catalyst via microwave Treatment. Powder Technology, 2018, 338: 764-773.

[21] Zilun Ma, Liyan Shi, Wenwen Qu*, Qiong Hu, Ruifang Chen, Yijun Wang and Zhen Chen. Microwave-assisted synthesis of an RGO/CdS/TiO2 step-scheme with exposed TiO2 {001} facets and enhanced visible photocatalytic activity. RSC Advances, 2020, 10, 43447–43458.

[22] Yu Ming yuan, Qu Wenwen*, Shengming Xu, Lu Wang, Bingguo Liu, Libo Zhang**, Jinhui Peng. Interfacial Stability, Electronic Property, and Surface Reactivity of α-MoO3/γ-Al2O3 Composites: DFT and DFT+U Calculations. Computational Materials Science, 2018, 153: 217-227 .

[23] Ye Xiaolei, Sivasankar koppala, Qu Wenwen*, Xu Shengming, Zhang Libo, Peng Jinhui. Microwave heating of Spent HDS Catalysts: microwave Sodium Roasting (MWSR)for In Situ Sulfur Fixation, Decarburization, and hot Water Leaching. Journal of the Taiwan Institute of Chemical Engineers. 2019, 97 : 146–157.

[24] Liu Yuan chen, Wang Dang, Xu Zhi Gang*, Separation and analysis of ascorbic acid racemates in drugs, Basic & Clinical Pharmacology & Toxicology, 2018, 122(S2): 28.